VNCviewer is a crossplatform remote desktop viewer - lets you interact with the remote machine's console session.
I don't know if Remote Desktop is a VNC based solution, but I'd guess it's more akin to Microsoft's Remote Desktop program (which doesn't interact with the remote console session, but starts a new user session with a local operator interface)
Unless Remote Desktop is a VNC derivative, it's nice to have both apps as they serve very different purposes. (plus, Microsoft's RemoteDesktop service isn't available on pre-XP machines, but VNC based services are)
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