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You can check both ways. On your PPC, goto activesync, if you see Exchange server entry there then you have configured that. To drill down, hit Menu->Configure Server->Next, hit Advance button, Next, you will see the Edit Server setting and you must uncheck the contacts to de-link it from Exchange server. After that I think you should be able to link it with your Outlook.
However, it has a problem because if you select removing sync contact with exchange server, it will delete your entire PIM, which is kind of sucks. Usually I would do is unpair with exchange then sync with office PC to get the contact back then sync with home PC. I am not sure after you de-link with the exchange server and restore your PIM will get all your contacts back or not. I would suggest to do a full backup and play with it.
Jeff
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