After playing with this for a bit, I gave up on it for the rest of the day. Today I plugged my phone into activesync; PIE used that data connection just fine, as well as a few other applications.
I don't think it was any setting I played with as nothing I did seemed to work when I was focusing on it. If I find out exactly what I did, I will post it, but all of my settings seem to be the same as when data over activesync was not working.
Note: the battery on my phone did run to 0% and turned itself off over the weekend.
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