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Just some added information. The exchange set up will require that "OMA" is enabled on your Exchange mailbox under the Exchange ActiveSync settings. The benifit to this service is you can synchronize your mail, contacts, and calendar information with your android.

Alternatively, if your mail administrators haven't or won't enable this you can configure the Droid to use POP or IMAP. Tertiary to this, you can also navigate to Outlook Web Access on your phone as long as your OWA site uses form based authentication as the Android platform isn't compatible with NTLM authentication (yet).