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You can only sync your device OTA with 1 Exchange Server, if you are sync'ing with your work server, then you cannot sync with Mail2Web.
You could always remove the work partnership, sync with mail2web to download your contacts, back them up with PIMBackup, and then remove the mail2web server and set up your work Exchange server again.
Then just restore your contacts with PIMBackup. It takes some work but it's a workaround...
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Samsung Epic 4G - LegendaryROM / Samurai kernel
ViewSonic gTablet - Flashback Honeycomb Alpha 10.1
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