I am not so sure it is possible any more... well put it this way, in the latest Active Sync I believe they took it out due to corporate security issues. I will try to find the link I read that in.
*edit: Found it.
http://www.microsoft.com/windowsmobi...ivesync41.mspx
Quote:
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Remote PC Sync (via Wifi or LAN) has been removed due to Enterprise customer feedback around security issues. If you are using this feature on a Windows Mobile 2003 powered device, please continue using ActiveSync 3.x or earlier.
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