russ10s, I don't see any reason why you cannot install the ROM with your wife's work PC and then once installed, use the iMac to sync again. I installed the ROM from one laptop running Vista, and then I installed a different radio version last night with an XP laptop. The ROM is going to take you to a fresh device look anyway, because it is a hard reset procedure. As an added suggestion, consider using an online exchange service, such as mail2web, to do over the air activesyncs. This service is free and it syncs your contacts, calendar, and emails. It makes hard resets so much less painful.
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